Affably Evil/Anime and Manga

"Robot: Excuse me. Your attention please. If you'd all be so kind as to follow me. We'll begin chopping you up. (Everyone gets scared) No no. It's not what you think. We don't want to hurt you. We only want the energy from your bodies to power the Big Gete Star. So we just have to chop you up."
 * Most Bobobo villains tend to be this and oddballs who often join afro-ed hero in silly antics. Those who aren't this are usually more serious and Faux Affably Evil.
 * Most major villains in Kaze no Stigma are very composed and polite even while making their destructive intentions clear.
 * Tokyo Babylon and X 1999, amongst their body of work, highlight CLAMP's apparent love for beautiful, charismatic, fashionable men doing good, honest work in the service of others with secret homicidal tendencies. Here's hoping it's not an instance Author Appeal.
 * Sakurazuka Seishiro is a friendly, charming, and generally mild-mannered veterinarian...when he isn't killing people on government contract with his dark onmyoujutsu and feeding their souls to a demonic cherry tree.
 * Also from X 1999 is Fuuma Monou, perfectly willing to indulge in "innocent enjoyments" when not busy reducing Tokyo into rubble bit by bit.
 * Also, Yuuto Kigai, similarly to Seishiro, has a cheerful, charismatic demeanor and works in the prefectural offices registering the birth certificates of newborns and the marriage licenses of newlyweds ... and is also a Dragon Of Earth who has no problems with fighting, destroying, or killing.
 * Headon from Tower of God. He withholds information,  and thus brings pain into Baam's life, but he sincerely welcomes Baam and anyone with enough balls to climb the Tower with a smile.
 * A couple of the antagonists in Saiyuki fit this. Homura may want to completely destroy and recreate heaven and earth, but he's genial and charismatic, and would rather Goku joined him than have to take him and his abilities by force. Ditto Hazel, only switch 'and recreate heaven and earth' with 'youkai' and 'Goku' with 'Sanzo.'
 * Patlabor
 * Patlabor 2: One of the people behind the terrorist attacks,, refuses to confess anything.   is also Affably Evil. He went to Kiichi Goto when Yukihito Tsuge decided to alter the plan and start a limited war that would topple the Japanese government.   original plan was a harsh political protest that used limited and controlled violence. Goto also agrees with   observations on the reality of peace, war, and political leaders exploit chaos instead of using a measured response.
 * Fullmetal Alchemist:
 * Greed, one of the homunculi who are collectively the antagonists of the series, won't put his fist on a woman, has a policy for always saying the truth, is respected and loyally followed by his comrades, and can even be nice if he wants to. That's not stopping him from being a pompous, greedy bastard and performing dubious acts for his own sake. He ends up doubling as a Noble Demon, especially the . It's probably because he's Greed. He is greedy for everything, which includes as many comrades/subordinates as possible, as he explains in the 2003 anime,  . He's quite protective of anyone or anything he considers his "property", and would rather admit defeat or run from battle than risk losing any of them to death or injury. Being a big humanity-hating jerk like the other Homunculi won't get him anywhere with that goal.
 * Father, the Big Bad, briefly becomes an Affably Evil Cloudcuckoolander when he absorbs Greed into himself. As soon as he creates a new Greed, though, he turns back into his irredeemable self.
 * From Dragonball:
 * Majin Buu as well. So cheerful and childlike that he doesn't seem to bear ill will towards anyone: he's just trying to have some fun; in fact, the moment it's pointed out to him that, you know, killing people by the millions isn't a nice thing to do, he (genuinely) promises to stop. At least at first...then his truly evil side takes over and he becomes an Ax Crazy Omnicidal Maniac who is a legitimate threat to the universe at large.
 * There's also the robot worker in "The Return of Cooler".

"Riful: My goal isn't your death. I will just torture you, make you awaken and then make you my friends! But if I kill you I lose everything. [She joins her hands in supplication] Please understand, I really do not wish to kill you!"
 * Also, Freeza's henchman, Zarbon, who is hinted to be a prince in the game Dragon Ball Z: Tenkaichi Tag Team.
 * Goku's father, Bardock, falls into this trope. He has a surprisingly relaxed personality for a Saiya-jin, and he visibly gets on well with his teammates, going as far to avenge them when Frieza's henchmen kill them. Oh, and he commits mass genocide for a living.
 * From One Piece:
 * Admiral Kizaru is incredibly polite, as when he asked a pirate who shot a bullet at him, as it was passing through his head, where his subordinate was. When they replied by running away, he saw no choice but to kick an entire mangrove tree down in a light-based explosion. Light Is Not Good, indeed.
 * of CP9 is equally polite and very honest. Before his identity as a villain was revealed, many fans speculated that he would be the shipwright to join the crew.
 * Friendly Punch Clock Villain Mr. Two Bon Clay was a total asshole when acting as an enemy, cheerfully exploiting Sanji's weaknesses while mocking him about them and so on. Still one of the nicest entries under Villainous Crossdresser, even before his Heel Face Turn. He is also completely bananas.
 * Hild from Ah My Goddess. She is a goddess' mother, very playful, very powerful, likes to hug people...and the queen of Hell. Her affability is more potent than most on this list. It's also heavily implied that she performs some notable..."good" in her role -- she effectively keeps Hell's more aggressive and (self-)destructive tendencies under wraps, and even negotiated a cease-fire with Heaven. She prefers a much more subtle Deal With the Devil means of furthering her goals than the open warfare some of her underlings seem to favor.
 * The Earl of Millennium from D Gray Man is a usually-jovial, eccentric gentleman who loves his family. He also happens to be plotting to destroy the world. His army is also Powered By a Forsaken Child. His Noah lieutenants (especially Tyki Mikk) fall into this occasionally as well, but just as frequently fall out.
 * Fin Kruder of Rental Magica is so affably evil that Itsuki and Honami eventually comment about how, though he can terrify them, they don't really hate him, despite what he puts them through. Either that, or he's well-meaning, but just that crazy. It's hard to tell in his case.
 * A recurring theme with the villain Sunshine in the Kinnikuman series. At first portrayed as just a standard member of his Quirky Miniboss Squad, in a later arc, Sunshine is genuinely moved by the displays of friendship between two of the heroes, because it turns out he feels the same way about his own friends. He even goes so far as to declare "Friendship exists even amongst demons!" at one point.
 * Claymore:
 * Riful is on a permanent recruitment drive and will frequently greet her opponents politely, proceed to make small talk with them, congratulate them for their efforts in their fight, and even give them tips on how to make a successful strike against her, all the while asking if they want to join her. When diplomacy fails, she just tortures them to the brink of death to force them to permanently give in to their Super-Powered Evil Side, all the while lamenting the pain she's inflicting and what a shameful waste of resources the death of the tortured would be.


 * Isely acts incredibly nice too. He helps people out on the road, offers them shelter from the cold, teaches them how to defend themselves, and orders his massive demon army to kill every living thing they see. Wonderful sort of guy.
 * Kazutaka Muraki from Yami no Matsuei is a polite doctor who approaches people in the most sympathetic manner when he is not.
 * From Death Note:
 * Light Yagami's girlfriend, Misa Amane, is this trope played straight. While Light is a deeply unpleasant person beneath his Stepford Smiler, Misa is a genuinely sweet, if somewhat ditzy, individual. That said, she is also seemingly unable to comprehend the fact that murder is fundamentally different from any other mundane activity.
 * Not to mention the shinigami - Ryuk loves video games and apples and considers Light his roommate, Rem is actually a genuinely nice person to anyone who's won her affection, and Sidoh seems like an ordinary guy. No, they don't give much of a damn for human life, but seeing as they have to kill humans to stay alive themselves, it's somewhat justified.
 * From the Mahou Sensei Negima manga:
 * Fate Averrancus is leading a group which is trying to carry out the destruction of his world. Despite this, he's actually a very sociable and polite young man, and Nodoka Miyazaki's mind reading artifact reveals that he would have rather preferred not harming anyone from her world, but
 * Earlier, there was Chao Lingshen, who gave the main hero the item of her eventual defeat as a simple thanks for his help. She was also more than willing to deliver a short, cheerful advertisement for her dim sum cart after a long pronouncement of evil towards the opposing army.
 * Many of the main Gundam villains are more or less affably evil. It'd be easier to list the utterly evil ones (and believe us, we've tried). Some of them are also Punch Clock Villains since they only fight because they are soldiers. Thinking about it...it's hard to come up with a straight example, as Gundam mostly lacks really evil people and many of its villains (and sometimes protagonists!) are mostly Well Intentioned Extremists.
 * If you want a straight example, there's Prime Minister Wong from G Gundam. A Manipulative Bastard with dashes of The Chessmaster and Mad Scientist (or at least, Mad Researcher), who loves red wine, chocolates, and sunglasses, and is also very polite and snarky to his rivals when in a good mood.
 * And before all of them...Ramba Ral from the original Mobile Suit Gundam.
 * In Gundam Seed, Andrew Waltfeld, is this at first. Thank to his immense popularity amongst fans, he miraculously "survived" from the death in war and did a Heel Face Turn.
 * Full Frontal from Mobile Suit Gundam Unicorn
 * Treize Kushrenada, a genuinely gentlemanly Magnificent Bastard, in Gundam Wing.
 * Takehiko Inoue's Vagabond has the Yoshioka clan, who seem to be one big happy group of True Companions who just have a penchant for cutting down or maiming those who besmirch the name of Yoshioka (and in the case of clan head Seijurou, ). The clan heads Seijurou, Denshichirou, and their right-hand man, Ueda Ryouhei, all get arguably sympathetic backstories, and they genuinely care about their followers and vice versa. Finally, when the first duel between Denshichirou and Miyamoto Musashi is interrupted by, Denshichirou tells Musashi to improve and then face him again in a year. (Unfortunately, Musashi ends up making far better use of that year than he does, leading him to .) Heck, after Ryouhei decides to have Musashi ambushed rather than let him leave Kyoto, during the ambush, one of the minor henchmen of the Yoshioka actually gets a flashback scene where Denshichirou is giving the henchman's younger self a good luck eel, since his wife was going to give birth soon! (Unfortunately, .)
 * Get Backers has two: Kagami Kyogi and Kuroudo Akabane. Both act like perfectly normal, polite people -- even while they're cutting people into bloody bits as a hobby (Akabane), or "observing" a 14 year old build WMDs and doing nothing to stop him (Kyogi).
 * Jo Jos Bizarre Adventure--
 * Dio Brando--at least, when his bloodlust for the Joestar family isn't in effect. His greatest weapon isn't his vampiric abilities, or even his ability to stop time. His biggest weapon is his pure charisma. This trait is emphasized in Pucci's flashbacks, which are through the eyes of a man who only knows of Dio's charm and charisma, and not his crossing of the Moral Event Horizon.
 * Dio's affable evilness is debatable, as it can be argued that he was only charming Pucci and playing with his emotions so he would make a more effective servant. He is definitely Faux Affably Evil, though.
 * Schneizel from Code Geass. You don't realize he's evil until . To top it all off, he undoes Lelouch's work of forty-something episodes in less than fifteen minutes - by . The fact that they're both Magnificent Bastards doesn't help. Schneizel has the advantage of hiding his manipulative nature well under his layer of Dissonant Serenity.
 * Around half the cast of Baccano falls under this, Lovable Rogue, or a combination of the two. Luck Gandor particularly exemplifies it, as he's generally an intelligent, amicable, and interesting bloke who is unfailingly polite even when he's telling someone he has no use for them whatsoever, and just happens to associate with absolute psychos and do horribly nasty things to guys who cross him.
 * is another great example; he's perfectly friendly, charming, and polite to people who he isn't currently trying to turn into bloody messes of gore.
 * Balalaika from Black Lagoon. This former Soviet special forces commander turned mob queen is generally calm, collected, funny, has only lost her temper once in the entire series, will occasionally spare people's lives on the grounds that they amuse her, and is usually willing to negotiate before resorting to violence. Of course, if said negotiations don't go her way, she won't even blink before casually gunning down everyone in the room.
 * ... And their families. And their little dogs too.
 * Hell, basically every major character in Black Lagoon is either this or a woobie
 * Askeladd from Vinland Saga is a nice enough guy, despite being a vicious murderer and raider.
 * Omamori Himari: Shuten Douji. In his first introduction to the main characters, he has a casual conversation with them...while putting everyone else in sight to sleep, and fighting the heroes with the intent to eat them.
 * Naruto has Akatsuki member Kisame Hoshigaki, an affable and genteel sharkman who will rip your fucking face off...but there's no reason to be rude about it. He's also arguably the Akatsuki's Only Sane Man.
 * Nagi from the Mai-HiME anime speaks in a relaxed tone and tends to address the heroines with polite words instead of taunting them. Naturally, a few of them suspect rather quickly that he's up to no good.
 * Miss Reiko Aya is a sweet, ditzy, very well-mannered White-Haired Pretty Girl who works as a music producer. She's also Sailor Aluminium Siren, Dark Action Girl, and a member of the Sailor Anima Mates under the leadership of Sailor Galaxia.
 * Some villains in Gun X Sword are like this.
 * First, there's Gadved, an actually kind pastor who saved Van's life previously, and who still tries, in the most affable way possible, to convert Van to the other side, but he kinda goes a bit batshit when he enters the battlefield...
 * Then, there's Fasalina, an ex-prostitute. Her speech is considerably kind and soft-spoken (it doesn't hide her malicious intents), and she doesn't lose her cool for the most of time...well, until, but even then, unlike the others whose Villainous Breakdown is going batshit, her breakdown is the 'affable' version of it: crossing the Despair Event Horizon. There's a really good illustration of Fasalina's affability in one scene. She and Carmen 99 are both seeking the services of the same electronics expert. While Carmen 99, one of the heroes, stiffs him of his full payment, Fasalina is a good tipper and thinks it terrible that someone would behave like that.
 * Also, in the same episode, contrast the Claw being a Friend to All Living Things and the behavior of the ruthless Jerkass hero, Ray. Despite the fact that at one point we see him murder a man, it is still impossible to see him as anything but a kind (maybe a little senile) old man.
 * From Slayers:
 * Xellos is so calm, friendly, cheerful, polite, and oftentimes funny that it's sometimes hard to believe that he's part of a race that's literally Always Chaotic Evil -- his kind feeds on the people's anger and suffering. But instead of hunting down and slowly killing humans, Xellos just tricks them and plays embarrassing or painful pranks while otherwise remaining so nice and helpful that his regular victims sometimes groan when he appears, but never tell him to get lost. This guy once wiped out a flock of dragons with but a gesture, and we see him shaken like a doll by some mortal he thoroughly frustrated...and smiling. He even saved some humans.
 * Red Priest Rezo is polite, well-mannered, and spends a lot of his time traveling from village to village, performing miracles as one of the world's best healers. He would also stop at literally nothing to heal his eyes, even disfiguring his own great-grandson as an experiment and putting the lives of thousands at risk.
 * Almost all Contractors in Darker Than Black are quite affable, when not on the job. To give a few examples:
 * November 11 can be a smug bastard and has a warped sense of humor, but is kind and protective of his partners, and brings a sort of amusing style to his job. Equally friendly and likable is his Bottle Fairy partner, April.
 * Amber, the seeming Big Bad of the first season, is a Magnificent Bitch in the body of a Deliberately Cute Child and does some pretty ruthless things while being quite cheerful and Moe
 * Amagiri, Amber's Dragon, is the quiet type of the Big Guy in personality, is really quite likable, and gets an amusing Please Put Some Clothes On scene with a hot female Contractor with no nudity taboo. He also participated in blowing up a series of embassy buildings.
 * The series also has human examples in Dr. Schraeder and Youko in the second season. He's a miniature senior citizen and she's a Moe nerd, and both are friendly people, but both are completely devoted to the mantra of For Science!, and are utterly amoral in this respect.
 * The Hakushuu Dinosaurs as a whole, a football team in Eyeshield 21. While you can't really be "evil" in football, they try their damndest, using very dirty tactics.
 * Marco, the quarterback, is a polite guy, drinks soda, offers under-the-table deals to other teams for the best of everyone, sends flowers to the enemy before a game, and is fighting for the love of his life, the team manager, Maria. However, he doesn't care if he's crushing other people's dreams. Or bones. Of all the team members, Marco best personifies this trope: Nice Guy off the field, but on the field, he uses tactics that would put SS stormtroopers to shame, relying on Gaou and Kisiragi to injure the other teams' players.
 * Kisiragi is a wilting Ill Boy, prone to frequent fevers and illnesses. He has loads of respect for Marco, a huge man-crush on Gaou, and is self-deprecating about his own abilities while lauding those of his opponents. He also suffers from a bad case of Blood Knight and In Love With Your Carnage, and plays with the intent of dislocating the arms of other receivers.
 * And King Evil himself, Gaou. He respects the rules and other players, and is pretty harmless off the field (unless you pick a fight deliberately). On the field, he turns his strength Up to Eleven and deliberately tries to smash everyone in his way.
 * Giovanni from Pokémon Special. Sure, he's the leader of a criminal organization that steals Pokemon and performs horrible experiments on them, but he has never resorted to dirty tricks when it comes to battling. When he fights Red, he's courteous, praising him and giving him pointers while beating the snot out of him. Hell, he even earnestly offered to fight at a disadvantage. This makes him a damn good villain because it shows he is where he is because he's just that strong. . This may show why he has a slew of extremely loyal Elite Mooks that refuse to take orders from anyone else claiming to be the new head of Team Rocket. In the HGSS arc,
 * Warrior King Guitar from Violinist of Hameln (the manga version, not the anime) is a heartless, thoroughly egotistical, mass-murdering monster, as befits a mazoku general, but his cheery, somewhat goofy demeanor, and fake humility make this less apparent than his colleagues. Well, until he starts torturing people while remaining as upbeat and polite as ever.
 * Mister Wiseman from Until Death Do Us Part is very courteous towards his enemies. He's also a college professor and criminologist when he's not plotting against people.
 * Many of the Demons/Supernaturals in Umineko no Naku Koro Ni qualify.  all demonstrate on a few occasions that they are much more human than they let on. Most of the Witches play with this trope at points (when they aren't cackling at murder) ...and then there's Erika.
 * And even she swoops in to save Ange in the last chapter and gives her some advice because of her pride as a "detective" (which is also why she accepted a ). Then again, there are more FaceHeelTurns, HeelFaceTurns, JerkassFacades, and personality twists and turns in this game than you can shake a stick at.
 * Maxamillion Pegasus from Yu-Gi-Oh. Although he mixes in enough Gentleman Snarker even when being affable that he's quite easy to hate.
 * From Kenichi the Mightiest Disciple, we have Agaard Jum Sai of Yami. Unlike his disciple, Tirawit Koukin (who is by far the coldest bastard in Yomi), Agaard is almost always smiling and cheerful,
 * Fortis of Huckebein from Magical Record Lyrical Nanoha Force, who is quite the cheerful, charming, and polite fellow, even when he's talking about the atrocities the Huckebein commit while trying to convince Tohma to join their criminal group.
 * In ROD the TV,.
 * Mononobe from Eden of the East. When he fails to recruit Takizawa Akira into his Evil Plan to attack Japan with missiles, he simply lets him go. When Takizawa beats him, he simply gives up and has a nice chat with Takizawa. This is mostly because he is a Well-Intentioned Extremist who actually believes his plans are the best for the country. Takizawa himself never actually blames him or calls him out on his extremist views; instead, he asks Mononobe for advice, and agrees with his Evil Plan, but amends it so that nobody dies.
 * Goemon in Yaiba, who, after all, enjoys drinking sake, and wouldn't hurt animals no matter what. Also, Kaguya, who flirted with Onimaru...before parrying his wind slash with her fan and tossing a huge ki blast at him.
 * Charles and Ray from Eureka Seven totally fit this trope. They're friendly, worldly, nice mercenaries for hire, who just happened to have a grudge against the good guys and were paid to take advantage of that. They honestly treat Renton better than most of the main characters, and they even plan on adopting him as their own son.
 * Sebastian Michaelis in Kuroshitsuji/Black Butler, although less so in the anime than in the manga.
 * Kirby Right Back At Ya's Customer Service/NME Salesman is so polite and funny at times that it's easy to forget that he wants Kirby dead, like Nightmare.
 * And speaking of Nightmare, even though he's bent on galactic domination, he's an oddly enough laid-back sort of tyrant who spends much of his time in his lair. He treats some of his employees, like the NME Salesman, with respect, and those he respects treat him with deep respect as well.
 * Old Super Robot Genre shows usually has a villain like these. The most standout example are Getter Robo and Great Mazinger, whose their motif for what they do in the show can be simply put as "They are not human." Otherwise, they are just as honorable and heroic as the heroes.