Five-Man Band/Anime N-R

Naruto: The Sasuke Retrieval Squad is a five-man band mined from four groups of 3-person five-man-bands. Some hats get swapped in the process.
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And in the Konoha History Arc Shippuden tends to fall this way:
 * The Leader||Shikamaru||
 * The Lancer||Naruto||
 * The Chick||Chouji||
 * The Smart Guy||Neji||
 * The Big Guy||Kiba||
 * Sixth Ranger||Rock Lee||
 * Team Pet||Akamaru||
 * The Leader||Shikamaru||
 * The Lancer||Naruto||
 * The Smart Guy||Sakura||
 * The Big Guy||Choji||
 * The Chick||Ino||
 * Sixth Ranger||Sasuke||
 * The Hero||Naruto||
 * The Lancer||Sai||
 * The Smart Guy||Kakashi||
 * The Big Guy||Yamato||
 * The Chick||Sakura||
 * The Sixth Ranger||Shikamaru||

Ninin ga Shinobuden
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 * The Hero||Shinobu||
 * The Lancer||Sasuke||
 * The Big Guy||Onsokumaru||
 * The Smart Guy||Miyabi||
 * The Chick||Kaede||

Noein: To Your Other Self
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 * The Hero||Yū Gotō||
 * The Lancer||Isami Fujiwara||
 * The Big Guy||Ai Hasebe||
 * The Smart Guy||Miho Mukai||
 * The Chick||Haruka Kaminogi||

One Piece: The Straw Hat Pirates
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 * The Hero||Luffy||
 * The Lancer||Zoro||
 * The Big Guy||Sanji (Also occasional Smart Guy), Franky and Chopper when he's in his chunky form||
 * The Smart Guy||Usopp, Robin, and Chopper (when he's being a doctor), sometimes Nami||
 * The Chick||Nami, sometimes Usopp||
 * Tagalong Kid & Team Pet||Chopper||
 * Team Mom/Cool Big Sis||Robin (initially a Sixth Ranger); previously Nami also held this position.||
 * Sixth Ranger||Brook||

And now we have the Jailbreak Gang, with some elements from a Five Bad Band as well:
 * The Hero||Luffy||
 * The Lancer||Mr. 2 Bon Kurei||
 * The Big Guy||Jinbei||
 * The Smart Guy||Buggy & Ivankov||
 * The Chick||Mr. 3||
 * Token Evil Teammate||Crocodile||
 * The Dragon||Mr. 1||
 * Sixth Ranger||Inazuma, who is Ivankov's Lancer.||

Ojamajo Doremi
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 * The Hero||Doremi||
 * The Smart Guy||Hazuki||
 * The Lancer||Aiko||
 * Tagalong Kid||Pop||
 * The Chick||Onpu||
 * The Big Guy||Momoko||
 * Sixth Ranger||Hana-Chan||

Ouran High School Host Club
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 * The Hero||Tamaki||
 * The Lancer||Kyouya (also The Smart Guy)||
 * The Big Guy||Mori and Hani||
 * The Smart Guy||Hikaru and Karou (who are also a bit of a The Lancer)||
 * The Chick||Haruhi (also the Sixth Ranger)||
 * Tagalong Kid||Honey||

Outlaw Star
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 * The Hero||Gene Starwind||
 * The Lancer||Jim Hawkings (also a The Smart Guy)||
 * The Big Guy||Aisha ClanClan||
 * The Smart Guy||Gilliam (also the Team Pet)||
 * The Chick||Melfina||
 * Sixth Ranger||Twilight Suzuka (even though she actually joined the crew before Aisha did)||

Pani Poni Dash
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 * The Hero||Rebecca Miyamoto||
 * The Lancer||Himeko Katagiri||
 * The Big Guy||Miyako Uehara||
 * The Smart Guy||Rei Tachibana||
 * The Chick||Sayaka Suzuki||
 * The Generic Guy||Kurumi Momose||
 * Sixth Ranger||Media||
 * Token Evil Teammate||Ichijou||
 * Team Pet||Mesousa||

Paradise Kiss
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 * The Heroine||Yukari "Caroline" Hayasaka||
 * The Lancer||Jouji "George" Koizumi||
 * The Big Guy||Arashi Nagase||
 * The Smart Guy|| Isabella Yamamoto||
 * The Chick||Miwako Sakurada||
 * Sixth Ranger||Hiroyuki Tokumori||

Petite Princess Yucie
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 * The Hero||Yucie||
 * The Lancer||Greta||
 * The Big Guy||Elmina||
 * The Smart Guy||Cocoloo||
 * The Chick||Beth||
 * Sixth Ranger|| ||

Pokémon
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 * The Hero||Ash Ketchum||
 * The Lancer / The Big Guy||Brock/Tracey Sketchit/Cilan||
 * The Smart Guy||Max||
 * The Chick||Misty/May/Dawn/Iris||
 * Team Pet||Pikachu||

Powerpuff Girls Z
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 * The Hero||Momoko/Blossom/Hyper-Blossom||
 * The Lancer / The Big Guy||Kaoru/Buttercup/Powered Buttercup||
 * The Chick||Miyako/Bubbles/Rolling Bubbles||
 * The Smart Guy/Tagalong Kid||Ken||
 * Mentor Archetype||Professor Utonium||
 * Team Pet||Poochi/Peach||
 * Sixth Ranger||Shirogane Z (Mojo Jojo mistakenly believes that is one)||
 * Note: In the original american version, Blossom also occupied the Smart Guy role.

Prétear - Leafe Knights
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 * The Hero||Hayate||
 * The Lancer||Sasame||
 * The Big Guy||Go||
 * The Smart Guy||Kei||
 * Tagalong Kids||Mannen, Hajime, and Shin||
 * The Chick / Eighth Ranger||Himeno (she's been chosen by the Leafe Knights)||
 * Team Pet||Tippi||

The Prince of Tennis - Seigaku version (again, more charas than in the usual Five Man Band, but they take turns at one or another role. This counts for all teams.)
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 * The Hero||Two: Ryoma Echizen and Kunimitsu Tezuka||
 * The Lancer||Takeshi Momoshiro (Echizen's Lancer), Shuusuke Fuji (Tezuka's)||
 * The Big Guy(s)||Eiji Kikumaru (also The Hero), Kaoru Kaidoh, Takashi Kawamura||
 * The Smart Guy||Sadaharu Inui||
 * The Chick||Syuichirou Oishi (also The Lancer to Eiji when they play)||
 * Team Pet(s) and Tagalong Kid(s)||Sakuno, Tomoka, the first years||
 * The Mentor||Ryuzaki-sensei, sometimes Nanjirou and Yamato||

The Prince of Tennis - Hyoutei version
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 * The Hero||Keigo Atobe||
 * The Lancer(s)||Ryo Shishido and Yuushi Oshitari||
 * The Big Guy||Munehiro Kabaji||
 * The Smart Guy||Yuushi Oshitari||
 * The Chick(s)||Gakuto Mukahi, Choutarou Ohtori (as the "nice one" or "mediator")||
 * Sixth Ranger||Hiyoshi Wakashi||
 * Sacrificial Lamb||Haginosuke Taki (actually "executed" by Shishido, to get back on the team)||
 * The Mentor||Tarou Sakaki||

The Prince of Tennis - Fudomine version
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 * The Hero and The Mentor||Kippei Tachibana||
 * The Lancer||Akira Kamio||
 * The Big Guy||Tetsu Ishida||
 * The Smart Guy||Shinji Ibu||
 * The Chick(s)||Masaya Sakurai, Kyousuke Uchimura, Tatsunori Mouri (mostly by default, but they have potential to fill other roles)||
 * Team Pet||An Tachibana||

The Prince of Tennis - Rikkaidai version
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 * The Hero||Seiichi Yukimura||
 * The Lancer||Genichirou Sanada||
 * The Big Guy||Akaya Kirihara (inversion via Unstoppable Rage since he's not as tall as the rest of the team members)||
 * The Smart Guy||Masaharu Niou, Hiroshi Yagyuu, Bunta Marui (self-proclaimed genius) and Renji Yanagi (The Genius Bruiser Yanagi is the most standard version, but )||
 * The Chick||Jackal Kuwahara (Team Mom version)||
 * Tagalong Kid||Shiita Urayama||

The Prince of Tennis - Shitenhouji version
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 * The Hero||Kuranosuke Shiraishi||
 * The Lancer||Kenya Oshitari (Lightning Bruiser)||
 * The Big Guy(s)||Gin Ishida (Genius Bruiser) and Kintarou Tooyama (not big, but he's ridiculously strong and a Genius Ditz Wild Child)||
 * The Smart Guy(s)||Koharu Konjiki and Hikaru Zaizen||
 * The Chick||Yuuji Hitouji (by default)||
 * Sixth Ranger||Senri Chitose||
 * The Mentor||Osamu Watanabe||

The Prince of Tennis - Yamabuki version
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 * The Anti Hero||Jin Akutsu||
 * The Lancer||Kiyosumi Sengoku||
 * The Big Guy(s)||Masami Higashikata, Kentarou Minami||
 * The Smart Guy(s)||Nitobe and Kita||
 * The Chick and Team Pet||Taichi Dan||
 * Sixth Ranger||Touji Muromachi||
 * Trickster Mentor||Mikiya Banda (aka Banji)||

The Prince of Tennis - Seigaku's Tagalong Kids can be seen as a Five Man Band, themselves
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 * The Hero and The Chick||Sakuno Ryuzaki||
 * The Lancer||Tomoka Osakada||
 * The Big Guy||Satoshi Horio||
 * The Smart Guy||Katsuo Mizuno||
 * The (other) Chick||Kachirou Kato||

Princess Tutu - Near the end
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 * The Hero||Mytho||
 * The Lancer||Princess Tutu||
 * The Big Guy||Autor||
 * The Smart Guy||Fakir||
 * The Chick||||

Psycho Busters - The young phychics
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 * The Hero||Kakeru||
 * The Lancer||Joi||
 * The Big Guy||Kaito||
 * The Smart Guy||Xiao Long||
 * The Chick||Ayano||

Psyren - The main group of Drifters
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 * The Hero||Ageha||
 * The Lancer||Oboro||
 * The Big Guy||Hiryuu (of the Genius Bruiser variety)||
 * The Smart Guy||Kabuto||
 * The Chick||Sakurako (but rather of the Lady of War kind)||
 * The Mentor||Matsuri||

Psyren - The Elmore kids
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 * The Hero||Fredrica (sometimes The Lancer to Marie)||
 * The Lancer||Shao (also The Smart Guy)||
 * The Big Guy||Kyle||
 * The Chick||Marie (sometimes The Hero)||
 * The Medic||Van||
 * The Sixth Ranger||Ageha||
 * The Mentor||Tenjuin Elmore||

Puella Magi Madoka Magica - subverted like hell, naturally
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 * The Hero / The Chick||Kaname Madoka||
 * The Lancer||Miki Sayaka||
 * The Big Guy||Akemi Homura||
 * The Mentor||Tomoe Mami||
 * Team Pet||Kyuubey||
 * Sixth Ranger||Sakura Kyouko||

Puella Magi Madoka Magica's Spin Off, Puella Magi Kazumi Magica, has the Pleiades Saints.
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 * The Hero||Saki Asami (clearly the one in charge)||
 * The Lancer||Nico Kanna (with some elements of The Smart Guy)||
 * The Smart Guy||Umika Misaki (with some elements of The Lancer)||
 * The Big Guy||Kaoru Maki and Mirai Wakaba||
 * The Chick||Satomi Usagi||
 * The Heart||Kazumi ||
 * Team Pet|| ||

Real Bout High School - The Shinsengumi
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 * The Hero||Ryoko Mitsurugi (The main character of the series)||
 * The Lancer||Aoi Asahina (Devout Catholic and Yamato Nadeshiko of sorts who knows G is in there somewhere)||
 * The Big Guy(s)||Megumi Momoi and Xiaoxing Huang (Tough grappler who puts herself though Training From Hell (with a pitching machine) and a tiny Anime Chinese Girl with Instant Knots)||
 * The Smart Guy||Midori Misato (The Cracker as a good guy)||
 * The Chick||Asuka Kuronari (Wannabe ninja; Extremely emotional)||
 * The Tagalong Kid||Hitomi Yuuki (Ryoko's best friend)||

The Record of a Fallen Vampire - Bridget's original group
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 * The Hero||Bridget (has elements of The Smart Guy as well)||
 * The Lancer||Renka||
 * The Big Guy||Fuuhaku (he's the physically biggest character in the series, though we never see what he looks like underneath)||
 * The Chick||Ethel (he's several centuries younger than all the members except Yuki)||
 * The Sixth Ranger||Yuki||

Record of Lodoss War - Parn's Party
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 * The Hero||Parn (Hot-blooded upstart swordsman. Originally wants to clear his father's name; later moves up to saving the world in general.)||
 * The Lancer||Etoh (Cleric; heals wounds, specializes in fighting ethereal demons. Shades of the Tagalong Kid.)||
 * The Big Guy||Ghim (Standard axe-wielding dwarf warrior. Makes up in strength what he lacks in height. Failure Knight.)||
 * The Smart Guy||Slayn (Wise wizard, old friend of Ghim. Occasionally pulls double duty as The Mentor.)||
 * The Chick||Deedlit (High elf fencer/elementalist. Parn's girlfriend.)||
 * Sixth Ranger||Woodchuck (Morally ambiguous thief, joins up last. Knife Nut.)||

Revolutionary Girl Utena - The Student Council functions like a warped version of a Five Man Band:
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 * The Hero||Touga (he's definitly not the Hero, but he's good at looking like one)||
 * The Lancer||Saionji||
 * The Big Guy||Juri||
 * The Smart Guy||Miki||
 * The Chick||Nanami||

Robotech: Second Generation (Super Dimension Cavalry Southern Cross)
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 * The Hero||Dana Stirling (Jeanne Francaix))||
 * The Lancer||Sean Phillips (Charles de Etouard)||
 * The Big Guy||Angelo Dante (Andrejz Slawski)||
 * The Smart Guy||Louie Nichols (Louis Ducasse)||
 * The Chick||Bowie Grant (Bowie Emerson)||

Robotech: Third Generation (Genesis Climber Mospeada)
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 * The Hero||Scott (Stick) Bernard||
 * The Lancer||Rand (Ray)||
 * The Big Guy||Lunk (Jim Austen)||
 * The Smart Guy||Lancer (Ironically)||
 * The Chick||Rook||
 * Tagalong Kid||Annie (Mint)||

Romeo X Juliet - The Capulet Resistence
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 * The Heroine||Juliet Fiamatta Asto Capulet||
 * The Lancer and The Big Guy||Curio||
 * The Smart Guy||Francisco||
 * The Chick||Cordelia (Team Mom)||
 * Tagalong Kid||Antonio (though he's more action-oriented than most) and later, Regan||
 * The Mentor(s)||Conrad (Team Dad), Lady Ariel, ||
 * Sixth Ranger(s)||Tybalt, Romeo||
 * Sacrificial Lamb|| ||
 * Sixth Ranger Traitor|| ||

Ronin Warriors
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 * The Hero||Ryo||
 * The Lancer||Alternatively Sage/Seiji and Cye/Shin, though the former better fits the mold||
 * The Big Guy||Kento/Shuu||
 * The Smart Guy||Rowen/Touma (ostensibly)||
 * The Chick||Mia/Nasuchi (Team Mom, also a bit of The Smart Guy and The Strategist thanks to her booksmarts. At times, Cye/Shin could also qualify.)||
 * Team Pet||White Blaze/Byakuen||
 * The Sixth Ranger|| ||
 * The Mentor||The Ancient One/Kaosu||
 * Tagalong Kid||Yuli/Jun||

Rosario to Vampire - The Newspaper Club
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 * The Hero||Tsukune/Inner Moka||
 * The Lancer||Kurumu||
 * The Big Guy||Mizore/Kokoa||
 * The Smart Guy||Ruby/Yukari||
 * The Chick||Outer Moka||
 * The Sixth Ranger||Gin/Fongfong||

Rose of Versailles
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 * The Hero||Oscar Francois de Jarjayes (the local Action Girl and main character)||
 * The Lancer||Andre Grandier (Oscar's childhood friend and borderline Morality Pet. He's more agreeable than most Lancers, though)||
 * The Big Guy||Alain de Soissons (to whom Oscar applies Defeat Means Friendship)||
 * The Smart Guy||Bernard Chatelet (fast in making plans and strategies, an Intrepid Reporter)||
 * The Chick||Rosalie Lamorliere (Oscar's close friend, very emotional and sensitive)||

Rurouni Kenshin
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 * The Hero||Kenshin||
 * The Lancer||Sanosuke||
 * The Big Guy||Yahiko (a Bratty Half Pint who can take one heck of a beating)||
 * The Smart Guy (Genius Bruiser)||Saito||
 * The Chick(s)||Kaoru, Misao||
 * The Sixth Ranger||Aoshi||
 * The Mentor||Hiko||
 * The Medic||Megumi||