Five-Man Band/Video Games T-Z

Tales of Destiny
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 * The Hero||Stahn||
 * The Lancer||Leon, Rutee ||
 * The Big Guy||Woodrow/Garr||
 * The Smart Guy and The Chick||Philia||

Tales of Eternia
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 * The Hero||Farah||
 * The Lancer||Reid||
 * The Big Guy||Max||
 * The Smart Guy(s)||Keele and Chat||
 * The Chick||Meredy||
 * Sixth Ranger Traitor||Ras||
 * The Mentor||Galenos||
 * Team Pet||Quickie||

Tales of Graces
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 * The Hero||Asbel||
 * The Lancer||Malik||
 * The Big Guy||Sophie||
 * The Smart Guy||Pascal||
 * The Chick||Cheria||
 * The Sixth Ranger||Hubert||

Tales of Hearts
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 * The Hero||Shing||
 * The Lancer||Hisui||
 * The Big Guy(s)||Innes, Kunzite||
 * The Smart Guy(s)||Kunzite, Innes||
 * The Chick(s)||Kohak, Beryl||
 * Mysterious Waif||Richea||
 * Sixth Ranger||Chalcedny Squad||

Tales of Innocence
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 * The Hero||Ruca||
 * The Lancer||Spada||
 * The Big Guy||Hermana||
 * The Smart Guy||Ricardo||
 * The Chick(s)||Iria, Ange||
 * Team Pet||Kouda||

Tales of Phantasia
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 * The Hero||Cless||
 * The Lancer||Chester||
 * The Smart Guy||Klarth||
 * The Big Guy||Arche (magic type)||
 * The Chick||Mint||
 * Sixth Ranger||Suzu (only available in re-releases of the game)||

Tales of Symphonia - Initial Guard
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 * The Hero||Lloyd||
 * The Lancer||Genis||
 * The Smart Guy||Raine||
 * The Big Guy||Kratos||
 * The Chick||Colette||
 * Sixth Ranger(s)||Sheena, Zelos, Presea and Regal||

Tales of Vesperia
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 * The Hero||Yuri||
 * The Lancer||Judith||
 * The Big Guy||Karol (who incidentally happens to be a 12-year-old kid.)||
 * The Smart Guy||Rita||
 * The Chick||Estelle||
 * Sixth Ranger||Raven||
 * Team Pet||Repede||

Throne of Darkness has seven men, of whom the player can control 4 at a time, while the others are resting. The ideal combination looks something like this:
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 * The Hero||The Leader||
 * The Lancer||The Swordsman or The Archer||
 * The Big Guy(s)||The Brick and The Berserker||
 * The Smart Guy||The Vizard or The Ninja||

Tomb Raider: Legend
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 * The Hero||Lara||
 * The Lancer||Winston||
 * The Big Guy||Zip||
 * The Smart Guy||Alister||
 * The Chick||Anaya||

Touch Detective
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 * The Hero||Mackenzie||
 * The Lancer||Chloe||
 * The Smart Guy||Cromwell||
 * The Chick||Penelope||
 * Team Pet||Fungi||

Touhou (as of Subterranean Animism)
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 * The Hero||Reimu||
 * The Lancer||Marisa||
 * The Smart Guy||Nitori and Patchouli||
 * The Big Guy||Suika||
 * The Chick||Alice||
 * Sixth Ranger||Aya and Sanae||
 * The Mentor||Yukari||
 * Team Pet||Rinnosuke||

The semi-canonical Touhou Team 9 is as follows:
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 * The Hero||Cirno (Idiot Hero)||
 * The Lancer||Wriggle||
 * The Smart Guy||Mystia||
 * The Big Guy||Daiyousei||
 * The Chick and Token Evil Teammate||Rumia||
 * Note: See also Five Bad Band for some of the boss teams in Touhou Project, who can technically fit here due to the games' White and Grey Morality.

Trauma Team
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 * The Hero||CR-S01||
 * The Lancer||Maria Torres||
 * The Big Guy||Hank Freebird (literally - his intro mission is called "The Big Guy")||
 * The Smart Guy||Gabriel Cunningham||
 * The Chick||Tomoe Tachibana||
 * Sixth Ranger||Naomi Kimishima||

Valkyria Chronicles
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 * The Hero||Welkin||
 * The Lancer||Alicia||
 * The Big Guy||Largo||
 * The Smart Guy||Isara||
 * The Chick||Rosie||

Valkyrie Profile 2 (at first)
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 * The Hero||Silmeria||
 * The Lancer||Rufus||
 * The Big Guy||Dylan||
 * The Smart Guy||Lezard||
 * The Chick||Alicia||
 * Sixth Ranger||Leone  and Arngrim||

Wild ARMs
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 * The Hero||Rudy (also the closest the group has to The Big Guy)||
 * The Lancer||Jack||
 * The Chick||Cecilia||
 * The Smart Guy||Hanpan||

The remake expands upon this to make it a full on 6 man team....er...5 with pet:
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Wild ARMS Alter Code F
 * The Hero||Rudy||
 * The Lancer||Jack||
 * The Smart Guy||Emma||
 * Action Girl||Jane||
 * The Chick||Cecilia||
 * The Sixth Ranger|| ||
 * Team Pet||Hanpan||

Wild ARMs 2
 * The Hero||Ashley Winchest||
 * The Big Guy||Brad Evans||
 * The Lancer||Kanon||
 * The Chick||Lilka Eleniak||
 * Kid Appeal Character||Tim Rhymeless||
 * The Sixth Ranger||Marivel Armitage||

Wild ARMs 3
 * The Hero / The Chick||Virginia||
 * The Lancer||Jet||
 * The Big Guy||Gallows||
 * The Smart Guy||Clive||

Wild ARMs 4
 * The Hero||Jude Maverick||
 * The Lancer and The Smart Guy||Arnaud G. Vasquez||
 * The Big Guy||Raquel Applegate||
 * The Chick||Yulie Ahtreide||
 * Sixth Ranger|| ||

Wild ARMs 5
 * The Hero||Dean||
 * The Lancer||Rebecca||
 * The Big Guy||Greg||
 * The Smart Guy||Avril||
 * The Chick||by virtue of process of elimination... Chuck||
 * Tagalong Kid||Carol||
 * In this case, I'm fully aware that the choices for The Smart Guy and The Chick are in YMMV territory, please feel free to suggest changes.

The Witcher 2 Assassins of Kings
 * The Hero||Geralt of Rivia||
 * The Lancer||Vernon Roche or Iorveth||
 * The Big Guy||Zoltan Chivay||
 * The Smart Guy||Dandelion||
 * The Chick||Triss Merigold||

The World Ends With You And, in the Alternate Universe bonus chapter:
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 * The Hero||Neku||
 * The Lancer||Shiki||
 * The Smart Guy||Joshua||
 * The Big Guy||Beat||
 * The Chick||Rhyme||
 * The Hero||Shooter||
 * The Lancer||Neku||
 * The Smart Guy||Joshua||
 * The Big Guy||Beat||
 * The Chick||Shiki||
 * Sixth Ranger Traitor|| ||

World of Warcraft Character Classes Alliance Alliance Expedition Horde The Artists Formerly Known as Level 80 Elite Tauren Chieftain
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 * The Hero||The Tank, leader and protector of the group.||
 * The Lancer||The Rogue, cat Druid and Hunter. Their methods are basically the opposite of the tank's, yet they're on the same side.||
 * The Big Guy||The Warrior, Paladin, balance Druid and Shaman. Whether it's because of heavy weapons and armor or hard hitting primal magic, these guys are anything but subtle.||
 * The Smart Guy||The Mage, Warlock, and Priest. They're Squishy Wizards with unique and varied magic.||
 * The Chick||The Healer, who deals little to no damage but instead keeps the group in a fit state to continue.||
 * The Sixth Ranger||The Death Knight, who joins the fight later in the timeline than the others. ||
 * The Hero||Varian Wrynn||
 * The Lancer||Magni Bronzebeard ||
 * The Smart Guy||Gelbin Mekkatorque||
 * The Big Guy||Tyrande Whisperwind||
 * The Chick||Velen or Jaina Proudmoore||
 * Sixth Ranger||Genn Greymane||
 * Tagalong Kid||Anduin Wrynn||
 * The Hero||Turalyon||
 * The Lancer||Danath Trollbane||
 * The Smart Guy||Khadgar||
 * The Big Guy||Kurdran Wildhammer||
 * The Chick||Alleria Windrunner||
 * The Hero||Thrall||
 * The Lancer||Vol'jin||
 * The Smart Guy||Lor'themar Theron||
 * The Big Guy||Cairne Bloodhoof ||
 * The Dark Chick||Sylvanas Windrunner||
 * Sixth Ranger||Trade Prince Gallywix (temporarily appointed by Thrall)||
 * The Hero||Samuro||
 * The Lancer||Bergrisst||
 * The Big Guy||Chief Thunder-Skins||
 * The Smart Guy||Mai'Kyl||
 * The Chick||Sig Nicious||

Syphon Filter: The Omega Strain
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 * The Hero||Cobra||
 * The Lancer||Gabe Logan||
 * The Big Guy||Gary Stoneman||
 * The Smart Guy||Teresa Lipan||
 * The Chick||Lian Xing||
 * The Mentor||Imani Gray||
 * The Sixth Ranger||Lawrence Mujari||

Winback
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 * The Hero||Jean-Luc Cougar||
 * The Lancer||Jake Hudson||
 * The Smart Guy||Tom Smith||
 * The Big Guy||Law Bruford||
 * The Chick||Lisa Roberts||
 * The Sixth Ranger||Mike Hawkins||
 * Tagalong Kid||Keith Birdy||
 * The Mentor||Steven Legal||

Xenosaga - Main party
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 * The Hero||Shion Uzuki||
 * The Lancer||Jr.||
 * The Big Guy||Ziggy and KOS-MOS||
 * The Smart Guy||Chaos||
 * The Chick||MOMO||
 * The Sixth Ranger||Jin Uzuki||

Ys Book I and II: Ancient Ys Vanished
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 * The Hero||Adol||
 * The Lancer||Goban||
 * The Big Guy||Dogi||
 * The Smart Guy||Luta||
 * The Chick||Lilia||
 * The Mysterious Waif(s)||Feena and Lair||
 * The Sixth Ranger Traitor||Keith||

Ys: The Ark of Napishtim
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 * The Hero||Adol||
 * The Lancer||Dogi||
 * The Big Guy||Chief Ord||
 * The Smart Guy||Ur||
 * The Chick||Olha||
 * The Cute Bruiser||Terra||
 * The Tagalong Kid||Isha||
 * The Rival||Geis||
 * The Obi Wan||Raba||

zOMG! features a number of ring classes that may fit the trope.
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 * The Hero||Melee - Single Target||
 * The Lancer||Buffs||
 * The Big Guy||Melee - Area of Effect||
 * The Smart Guy(s)||Crowd Control, Healing (sometimes The Chick)||
 * The Chick||Ranged||

Zork Grand Inquisitor
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 * The Hero||AFGNCAAP||
 * The Lancer||Dalboz of Gurth||
 * The Big Guy||Brog||
 * The Smart Guy||Griff||
 * The Chick||Lucy Flathead||
 * The Sixth Ranger||Antharia Jack||