Five-Man Band/Anime E-H

Et Cetera
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 * The Hero||Mingchao||
 * The Lancer||Baskerville||
 * The Big Guy||Benkate||
 * The Smart Guy||Fino||
 * The Chick||Yaghi||
 * The Sixth Ranger||Alternate (Also doubles as another The Smart Guy.)||

Eyeshield 21
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 * The Hero||Sena||
 * The Lancer||Monta||
 * The Big Guy||Kurita||
 * The Smart Guy||Hiruma||
 * The Chick||Mamori (Team Mom), later Suzuna (standard)||

Excel Saga (manga)
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 * The Hero||Matsuya||
 * The Lancer||Watanabe||
 * The Smart Guy||Sumiyoshi||
 * The Big Guy||Ropponmatsu I or II (depending on which one is working)||
 * The Chick||Iwata||

Excel Saga (anime)
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 * The Hero||Iwata||
 * The Lancer||Matsuya||
 * The Big Guy||Roponmatsu 1||
 * The Smart Guy||Sumiyoshi||
 * The Chick||Watanabe||
 * Tagalong Kid||Ropponmatsu 2||
 * Keep in mind that when they form into an actual team, its as a parody of Sentai heroes, so it's hard to figure out who actually fits the role and who is a parody of that role.

Fairy Tail
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 * The Hero||Natsu Dragneel||
 * The Lancer||Gray Fullbuster||
 * The Smart Guy||Happy||
 * The Big Guy||Erza Scarlet||
 * The Chick||Lucy Heartfilia||
 * Sixth Ranger||Elfman Strauss or Gajeel Redfox||
 * Tagalong Kid||Wendy Marvel||

The  from the latest Tournament Arc might just fit this trope better than the protagonists.
 * The Hero||Gajeel Redfox||
 * The Lancer||Juvia Loxar||
 * The Smart Guy|| ||
 * The Big Guy|| ||
 * The Chick||Mirajane Strauss||
 * Sixth Ranger||Cana Alberona||

Fang Of The Sun Dougram
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 * The Hero||Rocky||
 * The Lancer||Festa, later Crinn||
 * The Smart Guy||Crinn, later Henkel||
 * The Big Guy||Chico and/or Nanashi||
 * The Chick||Canary, later Rita||
 * Kid Appeal Character||Billy||
 * Tagalong Kid||George||
 * Team Pet||Nanashi||

Flame of Recca: Team Hokage
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 * The Hero||Recca Hanabishi||
 * The Lancer||Tokiya Mikigami||
 * The Smart Guy||Kaoru Koganei||
 * The Big Guy||Domon Ishijima||
 * The Chick (Action Girl)||Fuuko Kirisawa||
 * The Chick (The Medic)||Yanagi Sakoshita||
 * Team Mom||Kagehoshi||

Fullmetal Alchemist - The Military
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 * The Hero||Roy Mustang||
 * The Lancer||Lt. Riza Hawkeye (She's always by Mustang's side, serving as his sole confidante - she is also the highest ranked besides Mustang, and generally level-headed where the other guys are completely lost. She also keeps Mustang on track and serves as his bodyguard on occasion. Considering the implied relationship, she's almost a cross between being his Battle Butler and his Violently Protective Girlfriend.)||
 * The Big Guy||Lt. Jean Havoc (It seems Breda would be, but Havoc is the most experienced (aside from Hawkeye and Mustang) in combat. Serves more in this capacity in the manga then the anime, in the anime he serves as more of the team butt monkey or even the Chick then anything else.)||
 * The Smart Guy||Lt Heymans Breda, WO Vato Falman (He looks like the big guy, but truth is Breda is a tactical genius, though this is more an informed ability then anything else. He often does the espionage work for Mustang, including picking up Dr Marcoh, supervising illegal border crossings, and interrogating Maria Ross. Warrant Officer Falman might also count considering he has a photographic memory and a more 'Spock' like manner.)||
 * Tagalong Kid||Master Sergeant Kain Fuery (He's the techie, almost useless at fighting, and has the lowest rank of all the assembled team. He'd be the smart guy, except Breda and Falman are much smarter then he is. Often gets in the way when fighting breaks out.)||
 * The Mentor||Lt. Gen. Grumman (Specifically, Mustang's mentor in the manga.)||
 * Team Pet||Black Hayate||

Scar's group
 * The Anti Hero||Scar||
 * The Lancer||Mei Chang||
 * The Smart Guy||Dr. Marcoh||
 * The Big Guys||Jerso and Zampano (also count as Those Two Guys)||
 * The Chick||Yoki||
 * Team Pet||Xiao May||

Ed's later group
 * The Hero||Ed||
 * The Lancer(s)||Greedling||
 * The Smart Guy||Hohenheim (once he joins; before that Ed or Ling- Ed's smarter but Ling is the best battle strategist)||
 * The Big Guys||Darius and Heinkel (also count as Those Two Guys)||
 * Action Girl||Lan Fan||
 * The Mentor||Fuu||

Fushigi Yuugi: Suzaku warriors
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 * Big Good||Miaka||
 * The Hero||Tamahome||
 * The Lancer||Tasuki||
 * The Big Guy||Nuriko (slight subversion, he's a Cute Bruiser more than a standard Big Guy)||
 * The Smart Guy||Chichiri||
 * The Chick||Hotohori (Royalty, So Beautiful Its a Curse, fights like a Lady of War, sits out battle during the second half of the series.)||
 * The Medic||Mitsukake||
 * Tagalong Kid||Chiriko||

Future GPX Cyber Formula: Sugo Asurada
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 * The Hero||Hayato Kazami||
 * The Lancer||Miki Jounouchi (also the Cool Big Sis)||
 * The Smart Guy||Shinsuke Maki||
 * The Chick||Asuka Sugo||
 * Tagalong Kid||Ryohei Sumi (although he's not the youngest of the team)||
 * The Mentor||Tetsuichiro Kurumada (also Team Dad)||
 * Team Pet||V-8||
 * Sixth Ranger||Knight Schumacher/||

Gash Bell (After the Zophise arc)
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 * The Hero||Gash||
 * The Lancer||Umagon||
 * The Big Guy||Wonlei||
 * The Smart Guy||Kanchome||
 * The Chick||Tio||
 * The Sixth Ranger||Brago||

Gakkou no Kaidan
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 * The Hero||Satsuki Miyanoshita||
 * The Lancer||Hajime Aoyama||
 * The Smart Guy||Reo Kakinoki (odd case: he's got lots of booksmarts and technical knowledge, but is the one with MORE What an Idiot moments due to his lack of common sense)||
 * The Big Guy and The Chick||Momoko Koigakubo (she's a sweet Ill Girl and a Distressed Damsel, but is also the tallest and oldest of the group and has channelized powerful spirits  at least twice)||
 * Tagalong Kid||Keiichirou Miyanoshita||
 * The Mentor||Amanojyaku (also Team Pet) ||
 * Sixth Ranger||

Get Backers has a revolving cast of Loads and Loads of Characters. The main characters, Ban and Ginji, tend to stay the same, but who fills the other roles depends on who was tapped for whatever mission there is and what elements of their past are currently making hell for everyone.
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Divine Design arc
 * The Hero||Ginji||
 * The Lancer||Ban||
 * The Smart Guy||Himiko||
 * The Chick(s)||Hevn, Kazuki (Captured & brainwashed early on)||
 * The Mentor||Maria||
 * Sixth Ranger / The Big Guy||Juubei||

Get Backers - Kazuki's old gang, Fuuga (lit. "Elegance")
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 * The Hero||Kazuki||
 * The Lancer||Juubei||
 * The Big Guy||Toshiki||
 * The Smart Guy||Saizou||
 * The Chick (Team Mom)||Sakura||

Get Backers - IL Recovery Team
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 * The Hero||Ginji||
 * The Lancer||Ban||
 * The Big Guy||Shido||
 * The Smart Guy||Kazuki||
 * The Chick(s)||Himiko, Hevn||
 * Sixth Ranger||Akabane||

Get Backers - The Shiki (lit. "Seasons") Clan
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 * The Hero||Shido Fuyuki||
 * The Lancer||Amon Natsuki||
 * The Big Guy||Ryuho Agi||
 * The Chick (The Medic)||Kaoru Haruki||

Get Backers - Stradivarius Recovery Team
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 * The Hero||Ginji||
 * The Lancer||Ban||
 * The Big Guy||Hevn||
 * The Smart Guy||Madoka||
 * The Chick(s)||Natsumi, Paul||
 * Sixth Ranger||Shido||

Get Backers - Venus de Milo arc
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 * The Hero||Ginji||
 * The Lancer||Ban||
 * The Big Guy||Shido||
 * The Chick||Emishi||

Get Backers - VOLTS gang leaders
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 * The Hero||Ginji (Lightning Emperor)||
 * The Lancer||Masaki (Ruler of Light, Flash Master)||
 * The Big Guy||Shido (Beastmaster)||
 * The Smart Guy||Makubex (The Unknown Boy, Electric Brain)||
 * The Chick The (other) Smart Guy||Kazuki (Kazuki of the Strings, Prince of Fear)||
 * Collectively, Kazuki, Shido, Makubex and Masaki are known as the Four Kings.

Getter Robo (Original and G)
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 * The Hero||Ryoma Nagare||
 * The Lancer||Hayato Jin||
 * The Smart Guy and The Chick||Michiru Saotome||
 * The Big Guy||Musashi Tomoe, later Benkei Kurama||
 * Tagalong Kid||Genki Saotome||
 * The Mentor||Dr. Saotome||

Ginga Densetsu Weed (More of an entire pack, but still)
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 * The Hero||Weed||
 * The Lancer(s)||Jerome, Kyoushiro and GB||
 * The Big Guy||Hiro||
 * The Smart Guy(s)||Rocket and Tesshin||
 * The Chick||Reika||
 * Sixth Ranger(s)||Hook and Sasuke||
 * Tagalong Kid||Mel||

Ginga Nagareboshi Gin
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 * The Hero||Gin||
 * The Lancer(s)||John and Ben||
 * The Big Guy||Moss||
 * The Smart Guy||Smith||
 * The Chick||Cross||
 * Sixth Ranger(s)||Wilson and Hakuro||

Go Lion
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 * The Hero||Akira Kogane||
 * The Lancer||Isamu Kurogane||
 * The Big Guy||Tsuyoshi Seido||
 * The Smart Guy||Hiroshi (Chibi) Suzuishi||
 * The Chick||Princess Fala||
 * Sacrificial Lamb||Takashi Shirogane||
 * Sixth Ranger||Ryou Shirogane (Takashi's Backup Twin)||

Gravion
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 * The Hero||Touga (subverted: he's not the main character)||
 * The Lancer||Eiji (... he is)||
 * The Smart Guy||Eina||
 * The Big Guy||Mizuki (*ahem*)||
 * The Chick (subverted)||Luna||
 * Sixth Ranger||Leele||

Gunslinger Girl
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 * The Hero||Henrietta||
 * The Lancer||Rico||
 * The Smart Guy||Claes (Initially), Angelica||
 * The Big Guy||Triela||
 * The Chick||Claes (After her handler Raballo died, she could not participate in missions)||

Gunslinger Girl -Il Teatrino-
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 * The Hero||Triela||
 * The Lancer||Henrietta||
 * The Smart Guy||Angelica||
 * The Big Guy||Rico||
 * The Chick||Claes||

Gunsmith Cats
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 * The Hero||Rally||
 * The Lancer||Misty||
 * The Smart Guy||Becky||
 * The Big Guy||Bean||
 * The Chick||May||

Hamtaro
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 * The Hero||Hamtaro||
 * The Lancer(s)||Oxnard and Boss||
 * The Big Guy(s)||Howdy, Snoozer, and Stan||
 * The Smart Guy(s)||Dexter, Panda, and Maxwell||
 * The Chick(s)||Bijou, Pashmina, and Sandy||
 * Tagalong Kid(s)||Cappy and Penelope||
 * The Mentor(s)||Elder Ham and Auntie Viv||
 * Sixth Ranger(s)||Jingle, Sabu, and Pepper||

Heartcatch Pretty Cure
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 * The Hero||Tsubomi/Cure Blossom||
 * The Lancer||Erika/Cure Marine||
 * The Big Guy||Itsuki/Cure Sunshine||
 * The Smart Guy||Yuri/Cure Moonlight||
 * The Chick||All of the above||
 * The Mentor||Kaoruko||
 * Team Pet||Chypre, Coffret, Potpourri||

High School DXD: Occult Research Club
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 * The Hero||Issei Hyodo||
 * The Lancer||Yuuto Kiba||
 * The Big Girls||Akeno Himejima, Koneko Toujou, and Xenovia||
 * The Smart Girl and The Leader||Rias Gremory||
 * The Chick (The Medic version)||Asia Argento||
 * The Chick (Tagalong Kid version)||Gasper Vladi||
 * The Mentor||Azazel||
 * Sixth Rangers||Irina Shido, Rossweiss, and Ravel Phenex||

High School DXD: Chaos Brigade Vali's Group
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 * The Hero||Vali Lucifer||
 * The Lancer||Bikou||
 * The Big Girl||Kuroka||
 * The Smart Guy||Arthur Pendragon||
 * The Chick||Le Fay Pendragon||
 * Team Pet||Fenrir and Gogmagog||

Highschool of the Dead
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 * The Hero||Takashi||
 * The Lancer||Rei||
 * The Big Guy (Genius Bruiser)||Saeko||
 * The Smart Guy||Saya, Hirano (sometimes The Chick, sometimes The Mentor)||
 * The Chick (The Medic version)||Shizuka||
 * The Chick (Tagalong Kid version)||Alice||
 * Team Pet||Zeke||

Historys Strongest Disciple Kenichi - The Masters of Ryōzanpaku And the members of Shinpaku Alliance:
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 * The Hero||Akisame||
 * The Lancer||Sakaki||
 * The Big Guy||Apacahi||
 * The Smart Guy||Ma Kensei||
 * The Chick||Shigure||
 * Sixth Ranger||The One Man Army known as "The Elder"||
 * The Hero||Kenichii||
 * The Lancer|| ||
 * The Big Guy|| ||
 * The Smart Guy||Nijima||
 * The Chick||Miu||
 * Sixth Ranger||All the ||

Hunter X Hunter
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 * The Hero||Gon||
 * The Lancer||Killua||
 * The Big Guy||Leorio (Although he also functions as The Medic)||
 * The Smart Guy||Kurapika||
 * The Mentor||Wing, and later Biscuit||