Five-Man Band/Anime W-Z

Weiss Kreuz
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Aya||
 * The Lancer||Youji||
 * The Big Guy||Ken||
 * The Smart Guy||Omi||
 * The Chick||Manxx, Birman, Sakura, Aya-chan||

Wolfs Rain
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Kiba||
 * The Lancer / The Big Guy||Tsume||
 * The Smart Guy||Hige||
 * Tagalong Kid||Toboe||
 * The Chick||Cheza||
 * Sixth Ranger||Blue||

Worst - Umihoshi Household
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Hana||
 * The Lancer||Takumi||
 * The Smart Guy||Renji||
 * The Big Guy||Sakota||
 * Tagalong Kid||Toranosuke||

Yes! Pretty Cure 5: This one's weird. The girls have two completely different group dynamics, which form two distinct Five Man Bands. The left-hand FMB is normally seen when the group is acting as an ordinary group of True Companions and nothing more; when it's time to deal with matters more suited to a team of Magical Girls, like fighting the Monster of the Week, they switch to the right-hand FMB. (Well, except that Urara/Lemonade has a tendency to turn into a second Nozomi/Dream when the plot isn't focusing on either of them, putting her on the wrong side.)
 * border=0 cellpadding=0 cellspacing=0
 * The Chick||Nozomi||/||The Hero||Cure Dream||
 * The Big Guy||Rin||/||The Lancer||Cure Rouge||
 * The Hero||Urara||/||The Chick||Cure Lemonade||
 * The Smart Guy||Komachi||/||The Big Guy||Cure Mint||
 * The Lancer||Karen||/||The Smart Guy||Cure Aqua||
 * The Mentor(s)||Kouji and Natsu||/||Team Pet(s)||Coco and Nuts||
 * Additionally, Milk is a Team Pet for both, and Kurumi/Milky Rose is a Sixth Ranger for both.

Yu-Gi-Oh
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Yugi/Yami Yugi||
 * The Lancer||Jonouchi (Joey)||
 * The Big Guy||Honda (Tristan)||
 * The Smart Guy||Bakura (for season one), Rebecca (for season four), Kaiba (when he's not being a jerk)||
 * The Chick(s)||Anzu (Téa), Shizuka (Serenity)||
 * The Sixth Ranger||Otogi (Duke)||
 * The Mentor||Grandpa Mutou||
 * Cool Big Sis||Mai Kujaku (Valentine)||

Yu-Gi-Oh GX - The Loads and Loads of Characters never actually form any Five Man Band, but the opening credits always show Judai posing with the characters who would fit the roles:
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Judai||
 * The Lancer||2 -- Manjyome, Sho||
 * The Big Guy||Hayato, then Kenzan||
 * The Smart Guy||Misawa||
 * The Chick||Asuka, sometimes Rei||

Yu-Gi-Oh 5 Ds - If the five Signers/Team 5D's are considered the main band, they divide up as follows: After Episode 80 and during the start of the WRGP Arc:
 * border=0 cellpadding=0 cellspacing=0
 * The Hero and The Smart Guy||Yusei Fudo||
 * The Lancer||Jack Atlas||
 * The Big Guy||Crow (also a Sixth Ranger)||
 * The Chick(s)||Aki and Ruka||
 * Tagalong Kid||Rua||
 * The Hero||Yusei Fudo||
 * The Lancer||Jack Atlas||
 * The Big Guy||Crow||
 * The Smart Guy||Bruno||
 * The Chick||Aki and/or Ruka||
 * Tagalong Kid||Rua (or as of episode 142, the Eleventh Hour Ranger).||

Yuusha-Oh Gao Gai Gar (Brave Robos/Main Order Room)
 * border=0 cellpadding=0 cellspacing=0
 * The Hero(es)||GaoGaiGar, Koutarou Taiga||
 * The Lancer(s)||ChouRyuJin, Geki Hyuuma (?)||
 * The Big Guy||Goldymarg, Geki Hyuuma or Ushiyama Kazou||
 * The Smart Guy(s)||Volfogg, Entouji Kousuke, Shishioh Liger and Shishioh Leo||
 * The Chick(s)||TenRyuJin (?), Utsugi Mikoto and Swan White||
 * Team Pet(s)||Mic Sounders the 13th, Piggy||
 * Sixth Ranger(s)||Mic Sounders the 13th, Geki Hyuuma, ChouRyuJin, and especially King J-Der/All the non-Japanese ones||

Yu Yu Hakusho
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Yusuke||
 * The Lancer||Kuwabara (sometimes The Big Guy)||
 * The Big Guy||Hiei (sometimes The Lancer)||
 * The Smart Guy||Kurama||
 * The Chick||Koenma (Non Action Guy), Botan||
 * The Obi Wan||Genkai (also )||
 * The Chicks are covered below.

Yu Yu Hakusho: So many chicks that they make their own Five Man Band.
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Keiko||
 * The Lancer||Shizuru||
 * The Big Guy||Atsuko||
 * The Smart Guy||Botan||
 * The Chick||Yukina||

Zoids: Genesis
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Ruuji||
 * The Lancer||Rei Mii/Seijuurou||
 * The Big Guy||Garaga||
 * The Smart Guy||Ron Mangan||
 * The Chick||Kotona Elegance||
 * The Mentor||Ra Kan||

Zoids: New Century Zero
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Bit Cloud||
 * The Lancer||Brad Hunter||
 * The Smart Guy||Jamie Hemeros||
 * The Big Guy||Leena Toros||
 * The Mentor||Steve Toros||

Zoids: Guardian Force
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Van||
 * The Lancer||Irvine||
 * The Smart Guy / The Big Guy||Thomas, Smart by personality, but his Zoid is definitely Big||
 * The Chick||Fiona|