Five-Man Band/Web Original

Atop the Fourth Wall
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Linkara||
 * The Lancer||Iron Liz||
 * The Smart Guy||Pollo||
 * The Big Guy||Harvey Finevoice||
 * Tagalong Kid||90s Kid||

A Very Potter Musical
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Harry (He is the Chosen One but if that wasn't enough he is also an attractive, guitar playing, all around cool guy.)||
 * The Lancer||Draco (Harry's rival, he hates Harry mainly because he is cooler then him and is constantly trying to be cool and failing.)||
 * The Smart Guy||Hermione (The Only Sane Man in the show and is the geekiest.)||
 * The Big Guy||Ron (Has elements of The Lancer too, especially in his Jerkass tendencies in Act 1, but he is very much the muscle of the group.)||
 * The Chick||Ginny (Harry's Love Interest, she does genuinely cares for everyone (even Draco, whom the others can't stand) and inspires Harry when no one else can.)||

Decade
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Decade||
 * The Lancer||Blade||
 * The Smart Guy||Garren||
 * The Big Guy||Chalice||
 * The Chick||Leangle||

DC Nation
 * border=0 cellpadding=0 cellspacing=0

Titans South
 * The Hero(es)||Scarab and Static||
 * The Lancer(s)||Zachary Zatara, and Speedy when Scarab takes the hero role||
 * The Big Guy||Kid Devil||
 * The Smart Guy||Gear||
 * The Chick(s)||Miss Martian, and Kid Devil to an extent||
 * The Mentor||Raven||
 * The Sixth Ranger(s)||Aquagirl and Captain Marvel Junior||

The Freelance Astronauts
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Maxwell Adams||
 * The Lancer||Ferr||
 * The Smart Guy||Evek||
 * The Big Guy||pipes!||

It's A Mall World
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Dean||
 * The Lancer||Evan||
 * The Big Guy||Tracii||
 * The Smart Guy||Taylor||
 * The Chick||Harper||

Red vs. Blue At the end of Revelation. The League of Extremely Ordinary Gentlemen
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Sarge||
 * The Lancer||Tucker||
 * The Big Guy||Grif. For proof, watch him ||
 * The Smart Guy||Simmons||
 * The Chick||Caboose and possibly ||
 * Sixth Ranger|| ||
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Cyrus||
 * The Lancer||Leon||
 * The Smart Guy(s)||Beau, Randy, and Kristin||
 * The Big Guy(s)||Jason and Harris||
 * The Chick(s)||Grant and Cat||
 * Team Mom||Allison||
 * Tagalong Kid||Jason F||
 * Sixth Ranger||Everyone, after Jason||

Loading Ready Run In the ninth episode of commodoreHUSTLE, Kate deliberately sets this up with the West Coast Motherlovin' Gs.
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Kate||
 * The Lancer||James or "The Fixer."||
 * The Big Guy||Bill||
 * The Smart Guy||Jeremy||
 * The Chick||Matt (Who protests his role as "The Girl.")||

Spill.com
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Korey||
 * The Lancer||Leon||
 * The Big Guy||Cyrus||
 * The Smart Guy||Carlyle||
 * The Chick||Edie||
 * Team Pet||Co-Host 3000||

Super Stories (The Ultimate Justice Squad)
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||The Captain||
 * The Lancer||Helaron (Unusually, Helaron is not the squad's official second-in-command, but she's been there the longest and has a lot of respect within the group||
 * The Smart Guy||Seer||
 * The Big Guy||Longtooth||
 * The Chick||Mirror (the Captain's official second-in-command)||

Survival of the Fittest
 * border=0 cellpadding=0 cellspacing=0

The Intrepid Six
 * The Hero||Adam Dodd||
 * The Lancer / The Smart Guy||Hawley Faust||
 * The (other) Lancer / The Big Guy||David Jackson (while not the largest or strongest, he's the group's primary combat muscle. Mostly because Marcus doesn't do any fighting.)||
 * The (other) Big Guy||Marcus Roddy||
 * The Chick(s)||Madelaine Shirohara and Amanda Jones||

S.A.D.D Generation 1
 * The Hero||Neil Sinclair||
 * The Lancer||Evan Angler||
 * The Big Guy||Nigel Gillespie||
 * The Smart Guy||Ric Chee||
 * The Chick||Braden Marsh||

S.A.D.D Generation 2
 * The Hero||Neil Sinclair||
 * The Big Guy||Corbin Arlen||
 * The Lancer/The Chick||Matt Wittany||
 * The Smart Guy||Khrysta Lawrence||
 * The (other) Chick||Mary McKay||

S.A.D.D Generation 3
 * The Hero||Neil Sinclair||
 * The Big Guy||Corbin Arlen||
 * The Lancer / The Chick||Matt Wittany||
 * The (other) Chick||Mary McKay||
 * The Smart Guy / Sixth Ranger||Dominica Sharpiro||

(S.A.D.D Generation 4 was a Magnificent Seven)

Tales of MU
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Mack||
 * The Lancer||Stef||
 * The Big Guy||Ian||
 * The Smart Guy||Dee||
 * The Chick||Amaranth||
 * Tagalong Kid||Two||

Tasakeru
 * border=0 cellpadding=0 cellspacing=0
 * The Heart||Hanami (Could be considered The Chick.)||
 * The Hero||Zero (notable in that he's clearly The Hero but not the main character)||
 * The Lancer||Faun||
 * The Big Guy / The Smart Guy||Ashpaw||
 * Fifth Ranger||Drake||

Whateley Universe
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Chaka, any of the Kimbettes||
 * The Lancer||Lancer and Bladedancer||
 * The Big Guy||Tennyo and Shroud||
 * The Smart Guy||Phase||
 * The Chick||Fey||
 * Heroic Sociopath of Hello Kitty Fury||Generator (also The Chick, despite being not quite physically female)||
 * Averted in The Saga of Tuck: The Five Man Band plays actual music and doesn't solve mysteries or fight crime or alien robots. The characters who do (well, no robots) have shifting relationships and more complex types.

Zeldathon
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Pablo Duffman||
 * The Lancer||Andrey Wyzan||
 * The Big Guy||Rev. Johnny Midnite (a mix between Gentle Giant and Boisterous Bruiser)||
 * The Smart Guy||Julian Bravo||
 * The Heart||Sean Gonzalez||
 * The Chick||Amanda Cesario||
 * Sixth Ranger||Andrew Julian||
 * The Medic||Tina Lasorsa||
 * Team Pet||Loki||

Greek Ninja
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Sasha||
 * The Lancer||Daichi||
 * The Smart Guy||Dawson||
 * The Big Guy||Menelaos||
 * The Chick||Eleonora||

Cheat Commandos Adventures
 * border=0 cellpadding=0 cellspacing=0
 * The Hero||Gunhaver
 * The Lancer||Fightgar
 * The Smart Guy||Silent Rip
 * The Big Guy||Crackotage
 * The Chick||Foxface
 * Sixth Ranger||Ripberger, Reinforcements, and the Topplegangers
 * Team Pet||Firebert
 * Big Good||Flashfight
 * Sixth Ranger Traitor||Reynold/Scrawnjob