X-Men Origins: Wolverine/Awesome

Wolverine killing a helicopter with his claws. And then killing Zero by walking away and letting his claws spark against gravel, thus igniting the leaked heli fuel...Cue Unflinching Walk. Just plain beautiful.
- He also gets one later on when fighting Sabretooth after being reinforced with adamantium, owning him beautifully and mocking him while he does so.
Sabretooth gets one when he's taking a beating from teleporting mutant Wraith. Sabretooth smiles and says "You know, there's something I always wanted to tell you..." Then he reaches out to where he knows Wraith will be next, grabs him by the spinal column as he materializes, and finishes with "You're predictable." Spine-breaking ensues.
Wade Wilson gets his own CMoA scene. The future "Merc with a Mouth" walks into a room full of armed Mooks, katanas spinning to block bullets from either side, and proceeds to whoop ass. The best moment has to be when he sees that a mook is about to take a shot at him (via a reflection on one of his katanas), spins around as the shot is fired, and cuts the bullet in half. The two halves end up killing two mooks behind him, to boot.

Wade: Okay, people are dead now.