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=== [[War Machine (Comic Book)|War Machine]]/Lt. Col. James "Rhodey" Rhodes ===
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Tony Stark's best friend and military liaison. Rhodey tries to talk sense into Tony regarding his antics as Iron Man, and even offers to help him, but he would also prefer to use the War Machine armor only as a last resort.
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* [[All There in the Manual]]: Rhodey's first scenes didn't contain any explicit confirmations about whether or not he had become War Machine. However, one of the comics from the limited series includes a flashback of him as War Machine, helping Iron Man fight Crimson Dynamo.
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A young sidekick who fought alongside the legendary Captain America during World War II. Bucky's last WWII adventure ended with him and Cap on Red Skull's rocket, and Bucky sacrificing himself to prevent the bomb inside the rocket from killing Cap. {{spoiler|About seventy years later, the Cosmic Cube granted a wish Captain America subconsciously made that Bucky would have survived that explosion. He resurfaced in the present day, as Winter Soldier.}}
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* [[Actor Allusion]]: Scott Menville played another sidekick of a legendary superhero in ''[[Teen Titans (animation)|Teen Titans]]''.
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A Kree alien scientist stationed on Earth. His stay caused him to develop an appreciation for the planet, particularly a fondness for Carol Danvers. This has motivated him to try and convince the other Kree aliens that Earth could prove a valuable asset in the Kree/Skrull war.
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* [[Adaptive Armor]]
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=== [[Beta Ray Bill]] ===
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An alien warrior whose people and planet was destroyed by Surtur, making him one of the only survivors. Upon running into Thor, Bill discovers that he {{spoiler|is worthy to lift Mjolnir}}, and joins Thor in battle against Surtur's demons.
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* [[Badass]]: Even in his normal state, he was able to take Thor in a fight.
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An African-American superhero with a special harness allowing him to fly.
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* [[Badass Normal]]
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A freelance photographer for ''The Daily Bugle'', who secretly also becomes a street-level New York superhero with spider-powers. Even though he has fought crime since before the Avengers first teamed up, most of the public has difficulty trusting him, partly due to slandering articles in ''The Daily Bugle''.
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* [[Animal Motif]]: spider, of course.
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A warrior of Asgard and Thor's half-brother.
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* [[Badass in Distress]]: {{spoiler|In the season one finale when Loki has Balder and several other warriors captured and awaiting execution.}}
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A female warrior of Asgard who often fights alongside Thor.
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* [[Action Girl]]
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Fandral the Dashing, Hogun the Grim, and Volstagg the Voluminous, three Asgardian warriors that always fight as a group.
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* [[Badass Crew]]
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Leader of the Fantastic Four.
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* [[Badass Bookworm]]
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* [[Rubber Man]]
* [[Workaholic]]: His tendency to put experimentation over socializing gets lampshaded by Tony.
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'''Tony:''' {{spoiler|Leave of absence.}} Are you really this oblivious, or are you just the dumbest man on the planet? }}
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Reed Richards' girlfriend.
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* [[Action Girl]]
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Sue Storm's brother.
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* [[Attention Whore]]: "How could you not know this? I'm Johnny! Johnny Storm, the Human Torch?"
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Reed Richards' best friend.
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* [[Bash Brothers]]: With Hulk when they're not at each others' throats.
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=== [[Luke Cage, Hero for Hire|Luke Cage]] ===
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A Hero For Hire who finds himself and Iron Fist employed by Pym to try and recover his stolen equipment.
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* [[Deadpan Snarker]]
* [[Embarrassing Nickname]]: "Power Man".
* [[Made of Iron]]: He has unbreakable skin and ''really'' enjoys [[No Sell]]-ing villains who try to attack him.
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* [[Red Oni, Blue Oni]]: The red to Iron Fist's blue.
* [[Salt and Pepper]]: The pepper to Iron Fist's salt.
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=== [[Immortal Iron Fist|Iron Fist]]/Daniel Rand-K'ai ===
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A master martial artist and friend of Cage's who Pym also hires to track down the one who stole his Ant-Man equipment.
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* [[Chest Insignia]]
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=== [[Ant-Man]] II/Scott Lang ===
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An electrical engineer-turned bank robber-turned custodian who stole Hank Pym's Ant-Man suit to save his daughter, Cassie Lang, from Crossfire. Instead of having Scott go to jail for his latest bank robbery, Hank (along with Iron Fist and Luke Cage) helped him rescue Cassie, then allowed Scott to become the new Ant-Man. Iron Fist also invited Scott to join the Heroes For Hire.
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* [[Anti-Villain]]: [[Sliding Scale of Anti-Villains|Type II]].
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Leader of the Guardians of the Galaxy and the only actual human member in this incarnation.
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* [[Badass Normal]]
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A Halfworlder raccoon, weapons specialist and second in command of the Guardians of the Galaxy
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* [[Alliterative Name]]
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Possessor of the Soul Gem. Helps the Guardians locate cosmic anomalies.
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* [[Badass Longcoat]]
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The second Quasar, daughter of Captain Mar-Vell, and member of the Guardians of the Galaxy
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* [[Action Girl]]
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He is Groot!
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* [[Big Guy, Little Guy]]: The big guy to Rocket Raccoon's little guy.
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A Canadian mutant who served in World War II with Captain America. Now a member of the X-Men.
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* [[Early-Bird Cameo]]: James Howlett made some very short appearances in "Meet Captain America."
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